Synthesis, characterization, photophysical, and photochemical properties of novel zinc(II) and indium(III) phthalocyanines containing 2-phenylphenoxy units

Ali H. E. A., Piskin M., ALTUN S., DURMUŞ M., ODABAŞ Z.

JOURNAL OF LUMINESCENCE, cilt.173, ss.113-119, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 173
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.jlumin.2015.12.010
  • Dergi Adı: JOURNAL OF LUMINESCENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.113-119
  • Anahtar Kelimeler: Phthalocyanine, 2-Phenylphenol, Photochemical, Photophysical, Fluorescence, Singlet-oxygen, PHOTODYNAMIC ACTIVITY, SUBSTITUENTS, DERIVATIVES, BEHAVIOR
  • Marmara Üniversitesi Adresli: Evet

Özet

The synthesis of highly soluble and non-aggregated peripherally/non-peripherally Zn and In(OAc) phthalocyanines was achieved by 3-/ and 4-(2-phenylphenoxy)phthalonitrile as starting materials. The novel compounds were characterized by elemental analyses, FT-IR, H-1-NMR (for phthalonitriles), UV-vis and MALDI-TOF mass (for Pcs) spectroscopic techniques. Additionally, photophysical, photochemical and spectral properties of the phthalocyanines were reported. Especially, the indium(OAc) phthalocyanines showed good singlet oxygen quantum yields in DMSO and they can be appropriate candidates as Type II photosensitizers in photodynamic therapy (PDT) applications. (C) 2015 Elsevier B.V. All rights reserved.