A chemosensitive based ammonia gas sensor with PANI/PEO- ZnO nanofiber composites sensing layer


Konuk Ege G., AKAY SEFER Ö., YÜCE H.

Microelectronics International, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1108/mi-09-2022-0161
  • Dergi Adı: Microelectronics International
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, ABI/INFORM, Aerospace Database, Communication Abstracts, Compendex, Metadex, Civil Engineering Abstracts
  • Anahtar Kelimeler: Composites, PANI, Nanofibers, Gas sensor, Polymer, NANOCOMPOSITE, TEMPERATURE
  • Marmara Üniversitesi Adresli: Evet

Özet

Purpose: The purpose of this study is to investigate the ammonia sensing performance of polyaniline/polyethylene oxide (PANI/PEO) and polyaniline/polyethylene oxide/zinc oxide (PANI/PEO-ZnO) composite nanofibers at room temperature. Design/methodology/approach: Gas sensor structures were fabricated using micro-fabrication techniques. First, onto the SiO2 wafer, gold electrodes were fabricated via thermal evaporation. PANI/PEO nanofibers were produced by the electrospinning method and the ZnO layer was deposited by RF magnetron sputtering on the electrospun nanofibers as a sensing layer. Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were performed for characterization analysis of nanofibers. After all, gas sensing analysis of PANI/PEO and PANI/PEO/ZnO nanofibers was performed using an experimental setup at room temperature conditions. Findings: FTIR analysis confirms the presence of functional groups of PANI, PEO and ZnO in nanofiber structure. SEM images demonstrate beads-free, thinner and smooth nanofibers with ZnO contribution to electrospun PANI/PEO nanofibers. Moreover, according to the gas sensing results, the PANI/PEO nanofibers exhibit 115 and 457 s response time and recovery time, respectively. However, the PANI/PEO/ZnO nanofibers exhibit 245 and 153 s response time and recovery time, respectively. Originality/value: In this study, ZnO was deposited via RF magnetron sputtering techniques on PANI/PEO nanofibers as a different approach instead of in situ polymerization, to investigate and enhance the sensor response and recovery time of the PANI/PEO/ZnO and PANI/PEO composite nanofibers to ammonia. These results indicated that ZnO can enhance the sensing properties of conductive polymer based resistive sensors.