SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF NOVEL ARYL-DITHIOFLUOROPHOSPHONATE DERIVATIVES AND X-RAY STUDIES OF [(4-CH3OC6H4)(F)P(S)S-][PH4P+]


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Saglam E. G. , Celik O., Yilmaz H., Acar N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.187, ss.1339-1346, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 187
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1080/10426507.2012.685667
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.1339-1346

Özet

Potassium and tetraphenylphosphonium salts of novel aryldithiofluorophosphonic acids were synthesized. Lawesson's Reagent was allowed to react with KF in acetonitrile to yield the potassium salt of p-methoxyphenyldithiofluorophosphonic acid. Treatment of the latter with tetraphenylphosphonium chloride resulted in the formation of the tetraphenylphosphonium salt. The structures of the compounds were elucidated by FTIR, H-1, C-13, F-19, and P-31 NMR spectroscopy as well as by ESI-mass spectrometry. The molecular and crystal structure of the tetraphenylphosphonium salt, determined by single crystal X-ray diffraction, is also presented.