Novel phthalocyanines bearing 7-oxy-3-(3,5-difluorophenyl)coumarin moieties: Synthesis, characterization, photophysical and photochemical properties

Erdogan T., Bulut M., ÇAMUR M.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, cilt.300, ss.6-14, 2015 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 300
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.jphotochem.2014.12.005
  • Dergi Adı: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.6-14
  • Anahtar Kelimeler: Phthalocyanine, Coumarin, Zinc, Indium, Photodegradation, Singlet oxygen, PHOTODYNAMIC THERAPY, ZINC(II) PHTHALOCYANINE, INDIUM PHTHALOCYANINES, SUBSTITUTED GALLIUM, OPTICAL-PROPERTIES, COUMARIN, PHOTOSENSITIZERS, DERIVATIVES
  • Marmara Üniversitesi Adresli: Evet

Özet

Two novel phthalonitriles,7-(2,3-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (2), 7-(3,4-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (3), and corresponding zinc(II)-, indium(III) phthalocyanines were prepared. Additionally, photophysical (fluorescence quantum yields and lifetimes), photochemical (singlet oxygen generation and photodegradation under light irradiation) and spectral properties of the resulting peripherally/non-peripherally tetra 7-oxy-3-(3,5-difluorophenyl) coumarin substituted zinc (II) and indium (III) phthalocyanines (4-7) were investigated. All compounds (1-7) were characterized by elemental analysis, IR, H-1 NMR, mass and UV-vis spectral data. The obtained 7-oxy-3-(3,5-difluorophenyl) coumarin bearing pure zinc (II) and indium (III) phthalocyanine complexes were well soluble in organic solvents and displayed good singlet-oxygen generation and appropriate photodegradation. (C) 2014 Elsevier B.V. All rights reserved.