Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

Isci Ü., Caner C., Zorlu Y., Gurek A. G., DUMOULIN F., Ahsen V.

DALTON TRANSACTIONS, cilt.43, sa.48, ss.17916-17919, 2014 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 43 Sayı: 48
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1039/c4dt02412e
  • Dergi Adı: DALTON TRANSACTIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.17916-17919
  • Marmara Üniversitesi Adresli: Hayır

Özet

4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.