Subtle variations of the behavior of a silylated tetraethylene glycol-substituted Zn phthalocyanine towards acids

Onal E., Topal S. Z., Tarhouni M., Isci Ü., Bassem J., Ahsen V., ...Daha Fazla

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.20, sa.8-11, ss.1182-1189, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20 Sayı: 8-11
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1142/s1088424616500371
  • Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1182-1189
  • Anahtar Kelimeler: phthalocyanine, silyl, TBDMS, acid sensitivity, fluoride anion sensitivity, FLUORIDE IONS, PROTONATION, RECOGNITION, CYANIDE, SENSOR, WATER
  • Marmara Üniversitesi Adresli: Hayır

Özet

An organosoluble phthalocyanine substituted by four silylated tetraethyleneglycol chains was designed. This phthalocyanine become water-soluble after acid-promoted removal of the TBDMS moieties (which does not occur in acetonitrile), and is therefore a naked-eye observation system of acid aqueous media. Fluoride anion sensitivity based on the same principle proved unfortunately unsuccessful.