Subtle variations of the behavior of a silylated tetraethylene glycol-substituted Zn phthalocyanine towards acids
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.20, sa.8-11, ss.1182-1189, 2016 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 20 Sayı: 8-11
- Basım Tarihi: 2016
- Doi Numarası: 10.1142/s1088424616500371
- Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1182-1189
- Anahtar Kelimeler: phthalocyanine, silyl, TBDMS, acid sensitivity, fluoride anion sensitivity, FLUORIDE IONS, PROTONATION, RECOGNITION, CYANIDE, SENSOR, WATER
- Marmara Üniversitesi Adresli: Hayır
Özet
An organosoluble phthalocyanine substituted by four silylated tetraethyleneglycol chains was designed. This phthalocyanine become water-soluble after acid-promoted removal of the TBDMS moieties (which does not occur in acetonitrile), and is therefore a naked-eye observation system of acid aqueous media. Fluoride anion sensitivity based on the same principle proved unfortunately unsuccessful.