The synthesis and characterization of 1,2-dihydroxyimino-3,6-di-aza-8,9-O-iso-butylidene nonane and its complexes with Ni(II), Cu(II), Zn(II) and Cd(II)

Canpolat E., Kaya M., GÖRGÜLÜ A. O.

Polish Journal of Chemistry, cilt.76, sa.5, ss.687-694, 2002 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76 Sayı: 5
  • Basım Tarihi: 2002
  • Dergi Adı: Polish Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.687-694
  • Anahtar Kelimeler: Cd(II) complexes, Cu(II), Ni(II), Vic-dioxime, Zn(II)
  • Marmara Üniversitesi Adresli: Evet

Özet

1,2-Dihydroxyimino-3,6-di-aza-8,9-O-iso-butylidene nonane (H2L) was synthesized starting from 1,2-O-iso-butylidene-4-aza-6-amino hexane (RNH2) and antichloroglyoxime. Ni(II) and Cu(II) complexes of H2L have a metal:ligand ratio of 1:2 and the ligand coordinates through two N atoms, as do most of the vic-dioximes. However, Zn(II) and Cd(II) complexes of H2L have a metal:ligand ratio of 1:1 and one chloride ion and one water molecule are also coordinated to the metal ion. Structures of the ligand and its transition-metal complexes are proposed, according to elemental analyses, IR, 13C and 1H NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).