Synthesis and Characterization of Novel Zn(II) Dimeric Phthalocyanines

ABDURRAHMANOĞLU Ş., Bulut M., Bekaroglu O.

9th Eurasia Conference on Chemical Sciences, Antalya, Türkiye, 9 - 13 Eylül 2006, ss.361-362 identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Doi Numarası: 10.1007/978-1-4020-6955-0_42
  • Basıldığı Şehir: Antalya
  • Basıldığı Ülke: Türkiye
  • Sayfa Sayıları: ss.361-362
  • Marmara Üniversitesi Adresli: Evet

Özet

Starting with tetracyanodibenzo(1,4,7,10-tetrathia-(12-crown-4)) (1) and 4-nitro-1,2-dicyanobenzene (2), nitro-substituted dimeric phthalocyanine (3) was synthesized. In the second step, using hydrazine hydrate as a reductant, amine-substituted dimeric phthalocyanine (4) was synthesized from nitro-substituted dimeric phthalocyanine. Structrures of all synthesized compounds were determined by elemental analyses, UV/vis, H-1-NMR and IR spectroscopy.