HPLC-DAD Method for the Analysis of Synthetic Dyestuffs in Historical Textile Objects in Istanbul Naval Museum


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Karabulut Aslan S., Erdoğan G., Dölen E., Yurdun T., S. Mubarak .

JORDAN JOURNAL OF CHEMISTRY, cilt.19, sa.2, ss.79-89, 2024 (ESCI)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 19 Sayı: 2
  • Basım Tarihi: 2024
  • Dergi Adı: JORDAN JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.79-89
  • Marmara Üniversitesi Adresli: Evet

Özet

Abstract:
In this study, dyestuff analyses of 39 different historical textile artifacts
consisting of wool, silk and linen fibers in different colors obtained from the Istanbul
Maritime Museum were
carried out.
These objects were first analyzed considering that they
contained only natural dyestuffs in their structures.
The results showed, however,
that
natural dyes were present only in one of the examined samples
. Therefore, the analysis was
extended for synthetic dyes. For this purpose, a gradient HPLC
-
DAD method was
developed
using two solvents,
tetrabutylammonium hydrogen sulfate/ammonium acetate
and
tetrabutylammonium hydrogen sulfate/
methanol.
Fifty
-
seven tex
tile samples
containing 25 red, 29 green, 1 yellow and 2 blue colored fibers were removed from the
investigated objects, treated by the HCl extraction method and analyzed by the developed
method. Concerning natural dyestuffs, only carminic acid was detecte
d in a jacket from the
Abdulaziz period (Ottoman Empire 1861
1876). The results also revealed that two of the
studied samples have UV spectra similar to those of the synthetic dyestuffs Brilliant Blue
FCF and Acid Red 52 (Sulforhodamine B). In addition, th
e historical textile objects were
dated according to the information obtained from these results
.