Structural features of dibromobis(nicotinamide)zinc(II) complex


ŞAHİN E., İDE S., Ataç A., Yurdakul Ş.

Journal of Molecular Structure, cilt.616, sa.1-3, ss.253-258, 2002 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 616 Sayı: 1-3
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1016/s0022-2860(02)00346-0
  • Dergi Adı: Journal of Molecular Structure
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.253-258
  • Anahtar Kelimeler: Crystal structure, Infrared spectra, Nicotinamide, Pyridine ring
  • Marmara Üniversitesi Adresli: Hayır

Özet

A novel ligand complex of Zn(II) with nicotinamide (one form of niacine) and two bromine ions were synthesised and characterised on the basis of elemental analysis, Fr-IR spectroscopy and X-ray crystallography. Crystal system is monoclinic, space group C2/c (no: 15), cell parameters are a = 13.3535(9) Å, b = 6.3859(7) Å, c = 19.1940(19) Å, β = 101.75(3)°, V = 1602.5(3) Å3 and Z = 4. It has been proven that the nicotinamide ligands in the structure of the Zn(II) complex are coordinated to the metal ion with N atoms ([ZnBr2(na)2] where na: nicotinamide). © 2002 Elsevier Science B.V. All rights reserved.