PREPERATION AND CHARACTERIZATION OF NOVEL MODIFIED GRAPHENE OXIDE REINFORCED NANOCOMPOSITE MATERIALS BY SLA 3D PRINTER


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Akın E., Çakır M., Berberoğlu B.

2rd International Natural Science, Engineering and Materials Technology Conference, Kırklareli, Türkiye, 15 - 17 Eylül 2022

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Basıldığı Şehir: Kırklareli
  • Basıldığı Ülke: Türkiye
  • Marmara Üniversitesi Adresli: Evet

Özet

As well known, epoxy acrylate resins have been widely used in SLA 3D printers applications. Epoxy acrylate systems have generally consisted of bisphenol-A glycerolate diacrylate (epoxy acrylate resin) and 1,6-Hexanediol diacrylate (HDDA, reactive diluent resin). The purpose of this study is to develop novel epoxy acrylate systems for 3D SLA printers and observe the properties of produced materials. For this reason, novel modified graphene oxide phases were synthesized. First, graphene oxide was synthesized by Hummers method. Then aromatic diisocyanates (TDI;toluendiisocyanate and IPDI; isophorone diisocyanate) and 2-Hydroxyethyl methacrylate (HEMA) were reacted with graphene oxides in THF solvent. These modified graphene oxide solutions were entegrated into epoxy acrylate system.  Tensile, izod impact resistance, shore-D hardness, abrasive and density tests were applied to the produced materials. Considering of the results, substantial increases were observed in terms of tensile strength and modulus, izod impact resistance, taber abrasive resistance and shore-D hardness. Moreover, densities of the produced novel samples presented considerable increases.