Synthesis and electrochemical properties of crown ether functionalized coumarin substituted cobalt and copper phthalocyanines


Esenpinar A. A. , ÖZKAYA A. R. , Bulut M.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.696, no.24, pp.3873-3881, 2011 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 696 Issue: 24
  • Publication Date: 2011
  • Doi Number: 10.1016/j.jorganchem.2011.08.045
  • Title of Journal : JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Page Numbers: pp.3873-3881

Abstract

The synthesis of novel 6,7-[15-crown-5]-3-[p-(3,4-dicyanophenoxy)phenyl]coumarin (1)/6,7-[15-crown-5]-3-[p-(2,3-dicyanophenoxy)phenyl]coumarin (2) and their peripherally/non-peripherally cobalt and copper phthalocyanine complexes (3-6) have been prepared and characterized by elementel analysis, H-1-NMR, MALDI-TOF, FT-IR and UV-Vis spectral data. Fluorescence intensity changes of compound 1 and 2 have been determined by addition of Na+ or K+ ions at 25 degrees C in THF. The effect of substitution type on the redox and aggregation behaviour of the compounds was investigated by voltammetry and in situ spectroelectrochemistry. (C) 2011 Elsevier B.V. All rights reserved.