Extraction of titanium(IV) from aqueous hydrochloric acid solutions into alamine 336-m-xylene mixtures


Filiz M., Sayar A.

CHEMICAL ENGINEERING COMMUNICATIONS, cilt.193, ss.1127-1141, 2006 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 193 Konu: 9
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/00986440500354457
  • Dergi Adı: CHEMICAL ENGINEERING COMMUNICATIONS
  • Sayfa Sayıları: ss.1127-1141

Özet

Extraction of Ti(IV) from its aqueous hydrochloric acid solutions into organic Alamine 336-m-xylene systems was investigated. Extraction experiments were conducted with three different initial metal concentrations of 1, 3, and 6 mg/mL, each at three acidic molarities of 1, 5, and 10 M. It was observed that the extractability of Ti(IV) increases with increasing acidic molarities. Alamine 336 diluted with m-xylene was found to be a suitable extractant for Ti(IV) across this acidic range. In parallel, a mathematical model was developed to correlate metal extractability and Alamine 336 volume content. Optimal Alamine 336 contents were estimated for single-stage extraction.