Individual and Simultaneous Electrochemical Detection of Bisphenol A and Bisphenol S in Food Samples Using Triethylenetetramine Functionalized Multi-Walled Carbon Nanotubes

Cakici M., AVAN A. A., Filik H., KÖK YETİMOĞLU E.

FOOD ANALYTICAL METHODS, cilt.16, sa.1, ss.225-237, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 16 Sayı: 1
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1007/s12161-022-02409-w
  • Dergi Adı: FOOD ANALYTICAL METHODS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Agricultural & Environmental Science Database, CAB Abstracts, Compendex, Food Science & Technology Abstracts, INSPEC, Veterinary Science Database
  • Sayfa Sayıları: ss.225-237
  • Anahtar Kelimeler: Bisphenol A, Bisphenol S, Electrochemical sensor, Triethylenetetramine, Carbon nanotubes, Food analysis, METAL-ORGANIC FRAMEWORK, SELECTIVE DETECTION, MODIFIED ELECTRODE, SENSING PLATFORM, HUMAN URINE, SENSOR, WATER, MICROEXTRACTION
  • Marmara Üniversitesi Adresli: Evet

Özet

In this concept, multi-walled carbon nanotubes (MWCNTs) were functionalized by triethylenetetramine (TETA-MWCNTs), and the as-synthesized TETA-MWCNT materials were utilized for the simultaneous voltammetric detection of bisphenol A (BPA) and bisphenol S (BPS). The voltammetric behaviors were tested by cyclic voltammetry (CV) and square-wave voltammetry (SWV). The high-priority experimental parameters have been carefully optimized. The designed sensor exhibited exceptional electrocatalytic activity toward the oxidation of BPA and BPS and provided two well-separate oxidation peaks enough to quantify BPA and BPS in a binary mixture. The standard curve was linear over the concentration range of 1.0-30 mu M for both analytes. The detection limit was estimated to be 0.35 mu M and 0.56 mu M for BPA and BPS, respectively. The designed voltammetric sensor was successfully applied in simultaneous estimation of BPA and BPS in food samples.