Prediction of thermal degradation of biopolymers in biomass under pyrolysis atmosphere by means of machine learning

Kartal F., Dalbudak Y., ÖZVEREN U.

Renewable Energy, cilt.204, ss.774-787, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 204
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.renene.2023.01.017
  • Dergi Adı: Renewable Energy
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), CAB Abstracts, Communication Abstracts, Compendex, Environment Index, Geobase, Greenfile, Index Islamicus, INSPEC, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, DIALNET, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.774-787
  • Anahtar Kelimeler: Biopolymers, Biomass, Thermal degradation, Artificial neural networks, Biomass characterization, NEAR-INFRARED SPECTROSCOPY, LIGNOCELLULOSIC MATERIALS, LIGNIN CONTENT, CELLULOSE, MECHANISMS, KINETICS, WOOD, HEMICELLULOSE, DECOMPOSITION, CONVERSION
  • Marmara Üniversitesi Adresli: Evet

Özet

© 2023 Elsevier LtdBiomass is the most widespread among renewable energy sources and offers many advantages. However, the heterogeneous structure of biomass brings many disadvantages. Therefore, characterization of thermal degradation of biopolymeric structures in biomass such as hemicellulose (HC), cellulose (CL), and lignin (LN) is very important for the efficiency of any biomass-based thermal process. On the other hand, the characterization of these biopolymers requires various experimental procedures that consume resources and time. Artificial neural networks (ANN) as a machine learning approach provide a remarkable opportunity to identify patterns in the complex structure of biomass fuels and their thermochemical degradation processes. In this study, a new model was developed for the first time to generate differential thermogravimetric analysis (DTG) curves for HC, CL and LN in biomass using proximate analysis results of raw biomass. DTG curves were evaluated using a ANN model developed with the open-source “TensorFlow” library in Python software. ANN model performed excellently with R2 values above 0.998. The results show that the newly developed model can estimate the thermal degradation for any temperature, so that biopolymer fractions in the degraded biomass can be calculated immediately, which has not been reported before.