Synthesis and characterization of novel phthalocyanines bearing quaternizable coumarin

Cakici H., Esenpinar A. A., Bulut M.

POLYHEDRON, cilt.27, sa.18, ss.3625-3630, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 18
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.poly.2008.09.016
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3625-3630
  • Anahtar Kelimeler: Coumarin (2H-chromen-2-one), Fluorescence, Metal-free, Phthalocyanines, Zinc, ELECTROCHEMISTRY, DERIVATIVES
  • Marmara Üniversitesi Adresli: Evet

Özet

The synthesis of novel metal-free and zinc phthalocyanines with four 3-[(2-diethylamino)ethyl]-7-oxo-4-methylcoumarin dye groups on the periphery were prepared by cyclotetramerization of a novel 3-[(2diethylamino)ethyl]-7-[(3,4-dicyanophenoxy)]-4-methylcoumarin. The novel chromogenic compounds were characterized by elemental analysis, H-1 NMR, C-13 NMR, MALDI-TOF, IR and UV-Vis spectral data. The electronic spectra exhibit bands of coumarin identity along with characteristic Q and B bands of the phthalocyanine (Pc) core. The IR spectra of all the Pcs showed three characteristic intense bands, at 1704 cm(-1) for the lactone carbonyl and two bands at 1489-1604 cm(-1) for the conjugated olefinic system. (C) 2008 Elsevier Ltd. All rights reserved.