Effect of ethanol on the partition coefficient of cyclohexylacetate between bulk and cetyltrimethylammonium bromide micellar pseudophases


Tuncay M., Göktürk S.

SPECTROSCOPY LETTERS, cilt.30, ss.825-834, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 30
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00387019708001631
  • Dergi Adı: SPECTROSCOPY LETTERS
  • Sayfa Sayıları: ss.825-834

Özet

Variation of the partition coefficient of cyclohexylacetate (CA) was studied by a differential absorption spectroscopic method as a function of ethanol and (CTAB) cetyltrimethylammoniumbromide concentrations. Approach used was based upon the pseudo-two phase model, including effect of ethanol concentrations on the critical micelle concentration (CMC) of CTAB. Ethanol enhanced micelle formation of CTAB at concentrations below 1% by volume, had a slight inhibitory effect at higher concentrations and totally inhibited at a concentration above 15% by volume.