Removal of Lead and Cadmium Ions from Aqueous Solutions Using Sulphur and Oxygen Donor Ligand Bearing Hydrogels

Firlak M., KÖK YETİMOĞLU E., KAHRAMAN M. V., KAYAMAN APOHAN N., DENİZ S.

SEPARATION SCIENCE AND TECHNOLOGY, cilt.45, sa.1, ss.116-128, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 45 Sayı: 1
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1080/01496390903256208
  • Dergi Adı: SEPARATION SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.116-128
  • Marmara Üniversitesi Adresli: Evet

Özet

A new thiourea and urea functional monomers were synthesized. A series of hydrogels were prepared by photopolymerization. The hydrogels were used for the removal of Pb(II) and Cd(II) ions from aqueous solutions. The influence of the uptake conditions such as the pH, the time, and the initial feed concentration on the metal ion binding capacity of hydrogel was tested. The selectivity of the hydrogels towards the different metal ions was also tested. The adsorption isotherm models were applied. The limits of detection and quantification were calculated. The usability of the hydrogels for preconcentration studies were also investigated.