JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.13, sa.6, ss.747-752, 2009 (SCI-Expanded)
The synthesis of the iron phthalocyanine bearing four fused tetraaza macrocycles starting from N,N',N '',N'''-tetrakis(p-tolylsulfonyl)triethylenetetraamine and 1,2-dibromo-4,5-bis-(bromomethyl) benzene is reported. The exchange of protecting tosyl groups by acetyl groups was necessary to obtain iron phthalocyanine. The efficiency of iron phthalocyanine as oxidation catalyst was tested for the practically important oxidation of 2,3,6-trimethylphenol (TMP) at different reaction conditions.