Screening Fluorination Additives for Efficient Perovskite Light-Emitting Diodes

Xia Y., Zou C., Lou Y., Zhou Y., Nar A., Li Y., ...Daha Fazla

Advanced Materials, cilt.37, sa.3, 2025 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Sayı: 3
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1002/adma.202411231
  • Dergi Adı: Advanced Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, INSPEC, MEDLINE, Metadex, Civil Engineering Abstracts, Nature Index
  • Anahtar Kelimeler: blue emission, dipole moment, domain distribution management, fluorinated additives, light-emitting diodes
  • Marmara Üniversitesi Adresli: Evet

Özet

Fluorinated additives are proposed to address the issue of domain polydispersity in quasi-2D perovskites. However, the lack of established screening criteria for these additives necessitates a laborious and costly trial-and-error process. Herein, this work explores the behind nature for the first time how various fluorination in fluorinated additives affect domain distribution in quasi-2D perovskites. The studies reveal that fully fluorinated additives could suppress undesirable low-dimensional domains, facilitating efficient energy transfer, while partially fluorinated additives adversely cause deteriorated optical properties. The observed trend is ascribed to the molecular dipole moment of the fluorinated additives, offering a reasonable explanation for experimental phenomena that has never been reported before. By employing fully fluorinated additives, the fabricated sky-blue perovskite light-emitting diodes (PeLEDs) deliver a peak external quantum efficiency (EQE) of 20.38% (@488 nm), marking as one of the highest efficiencies reported to date. The finding provides a screening criterion for fluorinated additives to realize efficient PeLEDs.