Synthesis and Photoluminescence Properties of Sr2Be2B2O7 Doped with Dy3+, Sm3+, Tb3+, and Pb2+

Pekgozlu I., Karabulut H., Mergen A., Basak A. S.

JOURNAL OF APPLIED SPECTROSCOPY, cilt.83, sa.3, ss.504-511, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 83 Sayı: 3
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1007/s10812-016-0319-9
  • Dergi Adı: JOURNAL OF APPLIED SPECTROSCOPY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.504-511
  • Anahtar Kelimeler: inorganic borate, photoluminescence, X-ray powder diffraction, LUMINESCENCE PROPERTIES, EMITTING PHOSPHOR, COMBUSTION SYNTHESIS, OPTICAL-PROPERTIES, EU3+, FLUORESCENCE, SPECTROSCOPY, CRYSTALS, SPECTRA, IONS
  • Marmara Üniversitesi Adresli: Evet

Özet

Pure and Dy3+-, Sm3+-, Tb3+-, and Pb2+-doped Sr2Be2B2O7 materials were prepared by a solution combustion synthesis method. The phase analysis of all synthesized materials was carried out using powder XRD. The photoluminescent properties of Dy3+-, Sm3+-, Tb3+-, and Pb2+-doped Sr2Be2B2O7 materials were investigated using a spectrofl uorometer at room temperature. The fi rst luminescent material, Sr2Be2B2O7:Dy3+, emits 478-493, 573, and 661 nm upon excitation with 344 nm; Sr2Be2B2O7:Sm3+ emits 563-574, 599-613, 647-666, and 705-713 nm upon excitation with 395 nm; Sr2Be2B2O7:Tb3+ emits 489, 545, 584-591, and 622 nm upon excitation with 248 nm; Sr2Be2B2O7:Pb2+ emits 371 nm upon excitation with 281 nm. Also, the dependence of the emission intensity on the activator ion (Dy3+, Sm3+, Tb3+, and Pb2+) concentration for the Sr2Be2B2O7 was studied. It was observed that the concentration quenching of Dy3+, Sm3+, Tb3+, and Pb2+ in Sr2Be2B2O7 is 0.05, 0.02, 0.07, and 0.02 mol.%, respectively.