Synthesis, characterization, and photophysical and photochemical properties of 3-(4-phenyloxy)coumarin containing metallo- and metal-free phthalocyanines


Creative Commons License

Kartaloglu N., Esenpinar A. A. , Bulut M.

TURKISH JOURNAL OF CHEMISTRY, cilt.38, sa.6, ss.1102-1117, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Konu: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3906/kim-1405-84
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1102-1117

Özet

The synthesis of novel zinc, cobalt, indium, and metal-free phthalocyanines carrying four 3-(4-phenyloxy)coumarins in the periphery/nonperiphery were prepared by cyclotetramerization of 344-(3,4-dicyanophenyloxy)phenyl]coumarin (2)/3-[4-(2,3-dicyanophenyloxy)phenyl]coumarin (3). The novel chromogenic compounds were characterized by elemental analysis, H-1 NMR, mass spectra, F-IR, and UV-vis spectral data. The effects of the coumarin units on the zinc, indium, and metal-free phthalocyanine complexes (2a/3a, 2c/3c, 2d/3d) were also investigated.