Designing Coconut Oil Encapsulated Poly(stearyl methacrylate-co-hydroxylethyl metacrylate) Based Microcapsule for Phase Change Materials

OKTAY B., Basturk E., KAHRAMAN M. V., Apohan N.

CHEMISTRYSELECT, cilt.4, sa.17, ss.5110-5115, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 4 Sayı: 17
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1002/slct.201900340
  • Dergi Adı: CHEMISTRYSELECT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.5110-5115
  • Anahtar Kelimeler: Core-shell, coconut oil, encapsulation, phase change materials, UV-cured PCM, THERMAL-ENERGY STORAGE, N-OCTADECANE, COMPOSITES, STABILITY
  • Marmara Üniversitesi Adresli: Evet

Özet

Phase change material (PCM) is an effective energy storage application, which has a relatively low cost. In this study, bio-based PCMs were prepared by using two techniques: encapsulation and UV-curing. Encapsulated-PCM was synthesized by suspension polymerization with stearyl methacrylate (SMA) and hydroxyethyl methacrylate (HEMA). In encapsulation process, the microcapsules were prepared from poly(stearyl methacrylate-co-hydroxyethyl methacrylate) shell and coconut oil (CO) core. UV-cured form stable PCM was also prepared by radical addition polymerization of stearyl methacrylate, hydroxyethyl methacrylate and coconut oil. In UV-curing process as in the second process, coconut oil was trapped within the polymeric network without covalent bonding. Thermal storage feature of encapsulated-PCM and UV-cured form stable PCM was investigated. The melting enthalpy of encapsulated-PCM is 119J/g, which is higher than both the melting enthalpy of pure coconut oil (106J/g) and UV-cured form stable PCM (47J/g). Moreover, thermal degradation results of PCMs show that the maximum thermal decomposition temperature of encapsulated-PCM increased compared with UV-cured from stable PCM.