The synthesis, characterization and electrochemical behavior of transition metal complexes containing nitrogen heterocyclic sulphur donor ligand

GÖRGÜLÜ A. O., ÇELİKKAN H., Arslan M.

Acta Chimica Slovenica, cilt.56, sa.2, ss.334-339, 2009 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 2
  • Basım Tarihi: 2009
  • Dergi Adı: Acta Chimica Slovenica
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.334-339
  • Anahtar Kelimeler: Co(ii), Cyclic voltammetry, Ni(ii) and cu(i) complexes, Xanthate
  • Marmara Üniversitesi Adresli: Evet

Özet

1,3-di(2-methylpiperidino)propan-2-ol (ROH) was synthesized 1,3- dichloropropan-2-ol with 2-methlypiperidine. Potassium 1,3-di(2- methylpiperidino)propan-2-0-xanthate (ROCSSK) was obtained from the reaction of 1,3-di(2- methylpiperidino)propan-2-ol (ROH) with carbon disulfide and metallic potassium. All products were generally obtained in high yields. xanthate complexes of Co(II), Ni(II) and Cu(I) was synthesized in the medium water as [CoL2(H2O)2], [NiL2(H 2O)2].2H2O and [CuL].2H2O. The novel xanthate ligand and its complexes were defined by FT- IR, 1H and 13C NMR spectroscopies, elemental analyses, magnetic susceptibility and TGA techniques. [CoL2(H2O)2] and [NiL 2(H2O)2].H2O complexes were subjected to cyclic voltammetry using Pt working electrode and Ag/AgCl (3 M KCl) reference electrode.