Peripheral and non-peripheral-designed multifunctional phthalocyanines; synthesis, electrochemistry, spectroelectrochemistry and metal ion binding studies


GÜNSEL A., KANDAZ M., KOCA A., SALİH B.

POLYHEDRON, cilt.30, sa.9, ss.1446-1455, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 30 Sayı: 9
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.poly.2011.01.030
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1446-1455
  • Anahtar Kelimeler: Phthalocyanines, Aggregation, Metal sensor, Electrochemistry, In-situ spectroelectrochemistry, In-situ electrocolorimetry, SUBSTITUTED COBALT, MANGANESE, BEHAVIOR, PORPHYRAZINES, SPECTROSCOPY, VOLTAMMETRY, HYBRID, IRON
  • Marmara Üniversitesi Adresli: Evet

Özet

A novel type of ionophore ligands, 3'-(2,3-dihydroxypropylthio)-phthalonitrile and 4'(2,3-dihydroxypropylthio)-phthalonitrile, and their alpha- and beta-tetrasubstituted metallo phthalocyanines, (MPc), (M = Zn(II), Co(II), Mn(III)Cl, Fe(III)Ac, Cu(II)) have been prepared and fully characterized by elemental analysis, FT-IR, (1)H and (13)C NMR, and MS (ESI and Maldi-TOF). The complexes are soluble in both polar and non-polar solvents, such as MeOH and EtOH, THF, CHCl(3) and CH(2)Cl(2). The spectroscopic properties of the complexes are affected strongly by the electron-donating sulfanyl units on the periphery of the phthalocyanines. The cation binding properties of the complexes, for example using Ag(I) and Pd(II), were evaluated by UV-Vis spectroscopy and the results show the formation of polynuclear phthalocyanine complexes. Functional donors on the periphery of the zinc and copper complexes coordinate to Ag(I) and Pd(II) to give ca. a 2:1 metal-phthalocyanine complex binding ratio for the concentration of 2.5 x 10(-5) M (Pc) and 1.0 x 10(-3) M (Metal ions). Voltammetric and in-situ spectroelectrochemical studies were performed to characterize the redox behavior of the complexes. An in-situ electrocolorimetric method was applied to investigate the colors of the electro-generated anionic and cationic forms of the complexes. (C) 2011 Elsevier Ltd. All rights reserved.