Substituent effect on iron phthalocyanines as cyclohexene oxidation catalysts

Yüceel Ç., Şahin Z., Işci Ü.

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.26, sa.06N07, ss.452-457, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 26 Sayı: 06N07
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1142/s1088424621501285
  • Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica
  • Sayfa Sayıları: ss.452-457
  • Anahtar Kelimeler: Phthalocyanine, oxidation catalyst, iron, cyclohexene, olefin, NITRIDO DIIRON PHTHALOCYANINES, PHOTODYNAMIC THERAPY, HETEROJUNCTIONS, COMPLEXES, METHANE, WATER
  • Marmara Üniversitesi Adresli: Evet

Özet

The effect of electron withdrawing vs electron donating substituents on the catalytic activity of iron phthalocyanines was investigated using cyclohexene oxidation as a model reaction. We demonstrate that iron phthalocyanine with electron-withdrawing substitutents showed better conversion and selectivity into 2-cyclohexen-1-one (ON) oxidation products.