Substituent effect on iron phthalocyanines as cyclohexene oxidation catalysts
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, cilt.26, sa.06N07, ss.452-457, 2022 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 26 Sayı: 06N07
- Basım Tarihi: 2022
- Doi Numarası: 10.1142/s1088424621501285
- Dergi Adı: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica
- Sayfa Sayıları: ss.452-457
- Anahtar Kelimeler: Phthalocyanine, oxidation catalyst, iron, cyclohexene, olefin, NITRIDO DIIRON PHTHALOCYANINES, PHOTODYNAMIC THERAPY, HETEROJUNCTIONS, COMPLEXES, METHANE, WATER
- Marmara Üniversitesi Adresli: Evet
Özet
The effect of electron withdrawing vs electron donating substituents on the catalytic activity of iron phthalocyanines was investigated using cyclohexene oxidation as a model reaction. We demonstrate that iron phthalocyanine with electron-withdrawing substitutents showed better conversion and selectivity into 2-cyclohexen-1-one (ON) oxidation products.