A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Kandaz M., Coruhlu S., Yilmaz I., Ozkaya A. R.

TRANSITION METAL CHEMISTRY, cilt.27, sa.8, ss.877-883, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 8
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1023/a:1021359012365
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.877-883
  • Marmara Üniversitesi Adresli: Evet

Özet

A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E, E')-dichloroglyoxime. Mononuclear transition metal complexes of Ni-II, Cu-II, Co-II and Fe-II have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and trinuclear complexes was achieved with (UO2)-O-IV and Cu-II depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, H-1-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.