Synthesis and characterization of two 2-amino-5-alkyl-1,3,4-thiadiazolyl carbamate ligands and their Co(II), Ni(II), and Zn(II) complexes

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Atıf İçin Kopyala

GÖRGÜLÜ A. O., Çukurovali A.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.32, sa.6, ss.1033-1042, 2002 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 32 Sayı: 6
• Basım Tarihi: 2002
• Doi Numarası: 10.1081/sim-120005620
• Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1033-1042
• Marmara Üniversitesi Adresli: Evet

Özet

Two novel monodentate carbamate ligands derived from 2-amino-5-methyl-1,3,4-thiadiazole and 2-amino-5-ethyl-1,3,4-thiadiazole, have been prepared. The metal complexes of the ligands were prepared with the chlorides of Co(II), Ni(II) and Zn(II) in methanol as solvent. The ligands and their metal complexes have been characterized by elemental analyses, IR, 13C and 1H NMR spectra, and magnetic susceptibility measurements. All of the complexes are mononuclear. Thermal properties of the ligands and their complexes have been studied by thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC).