In-situ preparation and characterization of pyrrole and tert-butyl 1-pyrrole-carboxylate on barium titanate/poly(acrylonitrile-co-methylacrylate) nanoparticles

Sagirli, FATMA; Unsal, C.; Kayali, E.; Sarac, A.

doi:10.1016/j.reactfunctpolym.2015.12.012

In-situ preparation and characterization of pyrrole and tert-butyl 1-pyrrole-carboxylate on barium titanate/poly(acrylonitrile-co-methylacrylate) nanoparticles

Sagirli F. Z., Unsal C., Kayali E. S., Sarac A. S.

REACTIVE & FUNCTIONAL POLYMERS, cilt.100, ss.1-11, 2016 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 100
Basım Tarihi: 2016
Doi Numarası: 10.1016/j.reactfunctpolym.2015.12.012
Dergi Adı: REACTIVE & FUNCTIONAL POLYMERS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1-11
Anahtar Kelimeler: Nanostructures, Chemical properties, Surface properties, Barium titanate BaTiO3, CHEMICAL OXIDATIVE POLYMERIZATION, ACRYLONITRILE BASED COPOLYMERS, NANOCOMPOSITE SYNTHESIS, TITANATE NANOPARTICLES, ABSORBING PROPERTIES, METHYL ACRYLATE, COMPOSITES, POLYPYRROLE, CONDUCTIVITY, POLYACRYLONITRILE
Marmara Üniversitesi Adresli: Hayır

Özet

In this study, barium titanate BaTiO3-poly(acrylonitrile-co-methylacrylate) [P(ANco-MA)]-polypyrrole (PPy) (BaTiO3-[P(AN-co-MA)]-PPy) and BaTiO3-[P(AN-co-MA)]-poly(tert-butyl 1-pyrrole-carboxylate) (TBPy) (BaTiO3-[P(AN-co-MA)]-TBPy) nanocomposites were synthesized separately by in-situ emulsion polymerization in the presence of surfactant dopant dodecyl benzene sulfonic acid (DBSA). Particle size, yield, crystallinity, chemical structure and morphology were fully characterized and systematically studied.