The synthesis and complexation study of some novel 3-methoxyphenyl chromenone crown ethers using conductometry

Gunduz C., Salan U., Ozkul N., Basaran I., Cakir U., Bulut M.

DYES AND PIGMENTS, cilt.71, sa.3, ss.161-167, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 71 Sayı: 3
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1016/j.dyepig.2005.06.021
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.161-167
  • Anahtar Kelimeler: 3-aryl-chromenone crown ethers, couruarino crown ethers, synthesis, complexation, binary solvent, conductometry, COUMARIN DERIVATIVES, CATION-BINDING, ION-PAIR, CU(II), SODIUM, ZN(II), NI(II)
  • Marmara Üniversitesi Adresli: Evet

Özet

7,8-Dihydroxy-3-(3,4-dimethoxyphenyl)-2H-chromenoiies, 7,8-diliydroxy-3-(3,5-dimethoxyphenyl)-2H-chromenones and 7,8-dihydroxy-3-(3,4,5-trimethoxypheiiyl)-2H-chromenones, o-diliydroxy-3-iiiethoxyphenyicoumarins, were prepared from 2,3,4-trihydroxybenzaldehyde and corresponding methoxyphenylacetic acid in NaOAc/Ac2O, respectively. 3-Methoxyphenyl-7,8-dihydroxy-2H-chromenone reacted with the polyethylene glycol ditosylate or dichloride in CH3CN/alkali carbonate to afford [12]crown-4, [15]crown-5 and [18]crown-6-chromonones.