Axial binding and host-guest interactions of a phthalocyanine resorcinarene cavitand hybrid

TOPKAYA TAŞKIRAN D., DUMOULIN F., Ahsen V., Isci Ü.

DALTON TRANSACTIONS, cilt.43, sa.5, ss.2032-2037, 2014 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 43 Sayı: 5
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1039/c3dt52732h
  • Dergi Adı: DALTON TRANSACTIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2032-2037
  • Marmara Üniversitesi Adresli: Hayır

Özet

A Zn phthalocyanine-resorcinarene cavitand hybrid was prepared. The axial binding and host-guest interactions of this hybrid with a pyridinyl-pyrene were investigated by UV-vis and fluorescence spectroscopic means, revealing the encapsulation of the guest maintained by axial coordination to the Zn phthalocyanine. Energy transfer between the pyrene and the phthalocyanine was evidenced.